Site 1222

Site 1222 (13°48.98´N, 143°53.35´W; 4989 meters below sea level [mbsl]; Fig. F1) forms a south-central component of the 56-Ma transect drilled during Leg 199 and is situated ~2° south of the Clarion Fracture Zone in typical abyssal hill topography. On the basis of regional magnetic anomalies, we anticipated basement age at Site 1222 to be equivalent to Chron C25r or Chron C25n (~56-57 Ma) (Cande et al., 1989), which is slightly older than at Site 1219. At the outset of drilling at Site 1222, our estimate for total sediment thickness was ~115 m (Fig. F2). Based upon a fixed hotspot model (Gripp and Gordon, 1990, for 0- to 5-Ma Pacific hotspot rotation pole; Engebretson et al., 1985, for older poles) Site 1222 should have been located ~1° north of the equator at 56 Ma and ~4°N at 40 Ma. A nearby gravity core (EW9709-17GC), taken during the site survey cruise, recovered >5 m of red clay with a late-middle Miocene age on the basis of radiolarian biostratigraphy (Lyle, 2000). Deep Sea Drilling Project (DSDP) Site 42 located ~4° east of Site 1222, was not drilled to basement but contains a thin sedimentary section (~100 m thick) of upper Oligocene nannofossil ooze through middle Eocene radiolarian nannofossil ooze. In turn, DSDP Site 162 lies ~1° north of DSDP Site 42 and is situated on young crust (49 Ma) that contains ~150 m of clayey radiolarian and nannofossil oozes of early Oligocene-middle Eocene age. Site 1222 will be used to study the position of the Intertropical Convergence Zone in the late Eocene and Oligocene, to sample late Paleocene and early Eocene sediments in the central tropical Pacific Ocean, and to help determine whether or not there has been significant southward movement of the hotspots with respect to the spin axis prior to 40 Ma

Site 1220

Site 1220 (10°10.600´N, 142°45.503´W; 5218 meters below sea level (mbsl); Fig. F1) forms a southerly component of the 56-Ma transect drilled during Leg 199. It is situated about midway between the Clipperton and Clarion Fracture Zones in typical abyssal hill topography. On the basis of regional magnetic anomalies, we anticipated basement age at Site 1220 to be equivalent to Chron C25n (~56 Ma; Cande et al., 1989), slightly older than at Site 1219. At the outset of drilling at Site 1220, our estimate for total sediment depth was ~225 meters below seafloor (mbsf) (Fig. F2). Based upon a fixed hotspot model (Gripp and Gordon, 1990, for 0- to 5-Ma Pacific hotspot rotation pole; Engebretson et al., 1985, for older poles), Site 1220 should have been located ~3° south of the equator at 56 Ma and in an equatorial position at 40 Ma. Thus, Site 1220 should have been situated underneath the South Equatorial Current in the early Eocene. A nearby piston core (EW9709-13PC) taken during the site survey cruise recovered >16 m of red clay, with the base of the core dated as middle-early Miocene on the basis of radiolarian biostratigraphy (Lyle, 2000). Site 1220 will be used to study equatorial ocean circulation from the late Paleocene through the late Eocene during the early Cenozoic thermal maximum. Sediment records from this site will help to define the calcite compensation depth (CCD) and lysocline during the Paleocene-Eocene and Eocene-Oligocene transitions. In this and other respects, Site 1220 will act as an interesting analog to Site 1218. Both sites are thought to have been located on the equator at ~40 Ma, but the older crustal age anticipated at Site 1220 dictates a greater paleowater depth than for contemporaneous sediments accumulating at Site 1218

Site 1216

Site 1216 (21°27.16´N, 139°28.79´W; 5152 meters below sea level [mbsl]; Fig. F1) is situated in abyssal hill topography south of the Molokai Fracture Zone and two small associated unnamed parasitic fracture zones (Fig. F2). Based on magnetic lineations, Site 1216 appears to be situated on normal ocean crust formed during the C25r magnetic anomaly (~57 Ma; Atwater and Severinghaus, 1989). Site 1216 was chosen for drilling because it is near the thickest section of lower Eocene sediments along the 56-Ma transect, which was based upon the seismic stratigraphy of seismic reflection data acquired on site survey cruise EW9709 during transits between the proposed drill sites (Lyle et al., this volume; Moore et al., 2002). The Cenozoic history of sedimentation in this region was poorly constrained prior to Leg 199, being largely based on two Deep Sea Drilling Project (DSDP) drill sites (40 and 41) and piston core data (EW9709-3PC) from ~1.5° in latitude to the south. Based on data from these drill sites, we expected the sedimentary sequence at Site 1216 to comprise red clays (a mixture of wind-blown dust and authigenic precipitates) overlying a biogenic sediment section composed of an upper middle Eocene radiolarian ooze and lower carbonate ooze deposited when the site was near the ridge crest in the late Paleocene and early Eocene. The broad paleoceanographic objectives of drilling the sedimentary sequence anticipated at Site 1216 are as follows: (1) to help define the shift in the Intertropical Convergence Zone through the Paleogene by following the change in eolian-dust composition and flux through time (red clays) and (2) to help define the latitudinal extent, composition, and mass accumulation of plankton communities in the north equatorial Pacific region thereby constraining ocean circulation patterns and the extent of the equatorial high-productivity belt in the Eocene ocean. Results from Site 1216 will also provide important information to test whether there was significant motion of the Hawaiian hotspot with respect to the Earth's spin axis during the early Cenozoic. At 56 Ma, the backtracked location of Site 1216 based upon a hotspot reference frame (Gripp and Gordon, 1990, for 0- to 5-Ma Pacific hotspot rotation pole; Engebretson et al., 1985, for older poles) is about 9°N, 108°W. If significant hotspot motion or true polar wander occurred since 57 Ma (Petronotis et al., 1994), this drill site could have been much nearer to the equator

Site 1217

Site 1217 (16°52.02´N, 138°06.00´W; 5342 meters below sea level [mbsl]; Fig. F1) is one of seven sites drilled to target upper Paleocene crust along a latitudinal transect during Leg 199 and will be used to investigate paleoceanographic processes in the northern tropical early Eocene Pacific Ocean. Site 1217 is situated ~1° north of the Clarion Fracture Zone on abyssal hill topography typical of the central Pacific. Based on magnetic lineations, basement age at Site 1217 should be in magnetic Anomaly C25r or ~57 Ma (Cande et al., 1989; timescale of Cande and Kent, 1995). The Cenozoic history of sedimentation in this region was poorly constrained prior to Leg 199 drilling because the nearest drill site (Deep Sea Drilling Project [DSDP] Site 162) is situated ~300 km south and west on 48-Ma crust. Based on data from this early rotary-cored hole, magnetic anomaly maps, a shallow-penetration piston core near Site 1217 (EW9709-4PC), and seismic profiling (Fig. F2), we expected the sedimentary sequence at Site 1217 to comprise a relatively thick (25 to 35 m thick) section of red clays overlying a radiolarian ooze and a basal carbonate section with possible chert near basement (estimated total depth ~125-150 meters below seafloor [mbsf]) deposited when the site was near the ridge crest in the late Paleocene and early Eocene. Site 1217 was chosen because it is anticipated to have been located just outside of the equatorial region at 56 Ma, ~5°N, 106°W based upon a fixed hotspot model (Gripp and Gordon, 1990, for 0- to 5-Ma Pacific hotspot rotation pole; Engebretson et al., 1985, for older poles). On the same basis at 40 Ma, the site was located at ~8°N, 111°W. Thus, Site 1217 should help define the paleoceanography of the northern tropical Pacific, in particular locating the ancient North Equatorial Countercurrent (NECC) region. General circulation-model experiments for the early Eocene (see Huber, this volume) suggest that the NECC was a well-developed current during this time period. Other paleoceanographic and paleoclimatic objectives of drilling the sedimentary sequence anticipated at Site 1217 are as follows: (1) to help define the shift in the Intertropical Convergence Zone through the Paleogene by following the change in eolian dust composition and flux through time (red clays); (2) to help constrain the middle-late Eocene calcite compensation depth (CCD); and (3) to sample the Paleocene/Eocene (P/E) boundary, one of the most climatologically critical intervals of Cenozoic time. Recovery of deep-sea sediments from this time interval during Leg 199 is a high priority because the P/E boundary has never before been sampled in the central tropical Pacific Ocean. Results from Site 1217 will also provide important information to test whether there was significant motion of the Hawaiian hotspot, with respect to the Earth's spin axis during the early Cenozoic. At 56 Ma, the backtracked location based upon a hotspot reference frame is ~5°N, 106°W, and at 40 Ma is ~8°N, 106°W. If significant hotspot motion or true polar wander occurred since 57 Ma (Petronotis et al., 1994), this drill site could have been much nearer to the equator

Geochemical analysis of bulk marine sediment by Inductively Coupled Plasma–Atomic Emission Spectroscopy on board the JOIDES Resolution

Geochemical analyses on board the JOIDES Resolution have been enhanced with the addition of a Jobin-Yvon Ultrace inductively coupled plasma-atomic emission spectrometer (ICP-AES) as an upgrade from the previous X-ray fluorescence facility. During Leg 199, we sought to both challenge and utilize the capabilities of the ICP-AES in order to provide an extensive bulk-sediment geochemical database during the cruise. These near real-time analyses were then used to help characterize the recovered sedimentary sequences, calculate mass accumulation rates of the different sedimentary components, and assist with cruise and postcruise sampling requests. The general procedures, sample preparation techniques, and basic protocol for ICP-AES analyses on board ship are outlined by Murray et al. (2000) in Ocean Drilling Program Tech Note, 29. We expand on those concepts and offer suggestions for ICP-AES methodology, calibration by standard reference materials, data reduction procedures, and challenges that are specific to the analysis of bulk-sediment samples. During Leg 199, we employed an extensive bulk-sediment analytical program of ~600 samples of varying lithologies, thereby providing several opportunities for refinement of techniques. We also discuss some difficulties and challenges that were faced and suggest how to alleviate such occurrences for sedimentary chemical analyses during future legs

Using Core (mcd) to log (mbsf) depth miss-matches as a basis for interpreting core elastic rebound and re-calculating core physical properties. Results from ODP Leg 199 (abstract of paper presented at AGU Fall Meeting, San Francisco, 6-10 Dec 2002)

Leg 199 drilled a series of sites in the equatorial Pacific in order to investigate the paleoceanography of the Paleogene Pacific Ocean. The two deepest cored sites, (1218 and 1219) have provided continuous/near continuous spliced sedimentary sections and in situ wireline log data. Comparison of core to log data sets shows the familiar non-linear, increasing with depth, miss-match between the core (metres composite depth - mcd) and log (mbsf) depths and concomitant offset between core and log physical property data sets e.g. porosity, density, velocity. The depth miss-matches represent core expansion due to elastic rebound experienced by the sediments upon unloading i.e. removal of overburden stress, which is a function of the sediment void ratio and log of the effective in situ stress. The increasing depth offset observed between the 1218 core and log data is used to calculate an expansion index (C$_{r}$) for continuous discrete measurement intervals, down the core. The C$_{r}$ values are used to re-compress the core (mcd) depth scale and as expected provide a good match with the log (mbsf) depths. The C$_{r}$ values are also used to correct the core index property data, to in situ values. The quality of the corrected core index property data is good when compared with the in situ measured log data. C$_{r}$ values are dependent upon the sediment composition (especially the quantity of clay) and core light absorption spectroscopy (LAS) data collected on Leg 199, provides a continuous down-core record of sediment composition, in terms of the percent clay, carbonate and opal. A relationship between the C$_{r}$ values and the sediment LAS composition is established and is then applied to the Site 1219 core LAS data, allowing appropriate C$_{r}$ values to be assigned to continuous, discrete core intervals. These composition based C$_{r}$ values are then used to re-calculate the core (mcd) depths and correct the index property data to in situ values. The quality of the depth and index property corrections are checked by comparison with the in situ measured log data, and provide encouraging results

Site 1215

Site 1215 (26°01.77´N, 147°55.99´W, 5396 meters below sea level [mbsl]; Fig. F1) is the northernmost of seven sites drilled on the 56-Ma-crust transect during Ocean Drilling Program (ODP) Leg 199. It will be used to investigate paleoceanographic processes in the northern subtropical early Eocene Pacific Ocean. Site 1215 is situated north of the Molokai Fracture Zone on typical abyssal hill topography in an area of thin but continuous sediment cover (Fig. F2). Based on magnetic lineations, basement age at Site 1215 should be in the youngest part of Anomaly An26R, or ~58 Ma (Cande et al., 1989; timescale of Cande and Kent, 1995). The Cenozoic history of sedimentation in this region was poorly constrained prior to Leg 199 drilling because the nearest Deep Sea Drilling Project (DSDP) or ODP drill site (DSDP Leg 5) is >1000 km away. Based on data from these early rotary coring activities (together with magnetic anomaly maps, a program of shallow-penetration piston coring, and seismic profiling), we expected the sedimentary sequence at Site 1215 to comprise red clays (a mixture of wind-blown dust and authigenic precipitates) overlying a basal carbonate section deposited when the site was near the ridge crest in the late Paleocene and early Eocene. The broad paleoceanographic objectives of drilling the sedimentary sequence anticipated at Site 1215 are as follows: (1) to help define the shift in the Intertropical Convergence Zone through the Paleogene by following the change in eolian-dust composition and flux through time (red clays); (2) to help define the North Equatorial Current and North Pacific subtropical gyre processes (basal carbonates); and (3) sampling of the Paleocene/Eocene (P/E) boundary, one of the most climatologically critical intervals of Cenozoic time. Recovery of deep-sea sediments from this time interval was a high priority because the P/E boundary has never been sampled in the central tropical Pacific Ocean. Results from Site 1215 will also provide important information to test whether there was significant motion of the Hawaiian hotspot, with respect to the Earth's spin axis, during the early Cenozoic. At 56 Ma, the backtracked location based upon a hotspot reference frame (Gripp and Gordon, 1990, for 0- to 5-Ma Pacific hotspot rotation pole; Engebretson et al., 1985, for older poles) is ~11°N, 117°W. If significant hotspot motion or true polar wander occurred since 57 Ma (Petronotis et al., 1994), this drill site could have been much closer to the equator

Leg 199 explanatory notes

Information assembled in this chapter will help the reader understand the basis for our preliminary conclusions and also enable the interested investigator to select samples for further analysis. This information concerns only shipboard operations and analyses described in the site reports in the Leg 199 Initial Reports volume of the Proceedings of the Ocean Drilling Program. Methods used by various investigators for shore-based analyses of Leg 199 data will be described in the individual contributions published in the Scientific Results volume and in publications in various professional journals

Site 1219

ite 1219 (7°48.019´N, 142°00.940´W; 5063 meters below sea level [mbsl]; Fig. F1) is the southernmost site to be drilled on the 56-Ma transect during Leg 199 and is situated ~3° to the north of the Clipperton Fracture Zone on abyssal hill topography. The age of basement at Site 1219 was poorly constrained prior to Leg 199 because little reliable magnetic anomaly data are available between the Clipperton and Clarion Fracture Zones (Cande et al., 1989). At the outset of Leg 199, based on one interpretation of the location of magnetic Anomaly C25r (~57 Ma) (Petronotis et al., 1994), previous drilling, and assumed spreading rates, we estimated the age of basement at Site 1219 to be ~55 Ma. Site 1219 is the only site to be drilled during Leg 199 that features all of the seismic horizons identified for a Paleogene equatorial seismic stratigraphy (Lyle et al., this volume), and an estimate of sediment thickness at Site 1219 prior to drilling (based upon the seismic reflection profile; Fig. F2) was 270-290 meters below seafloor (mbsf), depending on which reflection was chosen as basement. Based upon a fixed hotspot model (Gripp and Gordon, 1990, for 0- to 5-Ma Pacific hotspot rotation pole; Engebretson et al., 1985, for older poles), Site 1219 should have been within 2° of the equator between 40 and 21 Ma and should have crossed the equator at 29 Ma. Thus, the sediments should record equatorial conditions from the late middle Eocene to the early Miocene. In addition, Site 1219 should provide an analog for Site 1218, except that it is on older deeper crust. Site 1219 will be used to study near-equatorial ocean circulation from the late Paleocene to the late Eocene including deepwater flow and sea-surface properties. Sediment records from this site will help to define the carbonate compensation depth (CCD) and lysocline during the Eocene-Oligocene transition and near the Oligocene/Miocene (O/M) boundary. Based on the results from a site survey piston core (EW3709-12PC; Lyle, 2000) taken a few kilometers to the southwest, we anticipated that Site 1219 passed below the CCD in the early Miocene. The basement at Site 1219 should have formed in the Southern Hemisphere, and changes in magnetic inclination at this site will be important to define the position of the equator in the early Eocene

Site 1221

Site 1221 (12°01.999´N, 143°41.572´W; 5175 meters below sea level (mbsl); Fig. F1) forms an equatorial component of the 56-Ma transect drilled during Leg 199 and is situated about three-quarters of the way between the Clipperton and Clarion Fracture Zones in typical abyssal hill topography. On the basis of regional magnetic anomalies, we anticipated the basement age at Site 1221 to be equivalent to Chron C25n (~56 Ma) (Cande et al., 1989), about the same age as Site 1220. At the outset of drilling at Site 1221, our estimate for total sediment thickness was ~150 meters below seafloor (mbsf) (Fig. F2). Based upon a fixed hotspot model (Gripp and Gordon, 1990, for the 0- to 5-Ma Pacific hotspot rotation pole; Engebretson et al., 1985, for older poles), Site 1221 should have been located about 1° south of the equator at 56 Ma (in an equatorial position at ~50 Ma) and ~2°N at 40 Ma. Thus, Site 1221 should have been situated underneath the South Equatorial Current in the early Eocene. A nearby piston core (EW9709-14PC) taken during the site survey cruise recovered >11 m of red clay with the base of the core containing a calcareous radiolarian ooze dated as early Oligocene age on the basis of radiolarian biostratigraphy (Lyle, 2000). Site 1221 will be used to study equatorial ocean circulation from the late Paleocene through the late Eocene during the early Cenozoic thermal maximum. Sediment records from this site will help to define the carbonate compensation depth (CCD) during the Paleocene-Eocene and Eocene-Oligocene transitions. In this and other respects, Site 1221 will act as an interesting analog to Site 1220. The two sites are situated on similar age crust and exhibit similar seismic-stratigraphic sequences, but Site 1221 is thought to have crossed the equator ~5 m.y. earlier than Site 1220, during latest early Eocene time (~50 Ma)